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Volume 17, January-1
 
 

Water, Volume 17, Issue 2 (January-2 2025) – 53 articles

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31 pages, 30865 KiB  
Article
Site-Specific Hydrogeological Characterization for Radiological Safety: Integrating Groundwater Dynamics and Transport
by Soo-Gin Kim, Hong-Il Kwon, Jeoung-Seok Yoon, Chan-Hong Kim, Hyo Heo and Chung-Mo Lee
Water 2025, 17(2), 186; https://doi.org/10.3390/w17020186 (registering DOI) - 11 Jan 2025
Abstract
The radiological impact of radionuclide transport via groundwater pathways at the Wolsong Low- and Intermediate-Level Waste (LILW) Disposal Center was estimated by considering site-specific characteristics, including hydrogeology, geochemistry, and land use. Human intrusion scenarios, such as groundwater well development, were analyzed to evaluate [...] Read more.
The radiological impact of radionuclide transport via groundwater pathways at the Wolsong Low- and Intermediate-Level Waste (LILW) Disposal Center was estimated by considering site-specific characteristics, including hydrogeology, geochemistry, and land use. Human intrusion scenarios, such as groundwater well development, were analyzed to evaluate potential pumping volumes and radionuclide migration pathways. Particular attention was given to the hydrological and geochemical aspects of radionuclide transport, with a focus on local aquifer heterogeneity, flow dynamics, and interactions with engineered barriers and surrounding rock formations that delay radionuclide migration through sorption and other retention mechanisms. Sorption coefficients (Kd), calibrated using site-specific geochemical data, were incorporated to ensure realistic modeling of radionuclide behavior. A hierarchical approach integrating scenario screening, particle tracking techniques, and mass transfer modeling was employed. Numerical simulations using FEFLOW ver. 7.3 and GoldSim ver. 14.0 software provided insights into near-field and far-field transport phenomena under well pumping conditions. The results revealed distinct spatial flux behaviors, where carbon-14 (14C) dominated near-field flux due to its high inventory, while technetium-99 (99Tc) emerged as the primary dose contributor in the far-field flux, owing to its anionic nature and limited sorption capacity. Additionally, under high-pH conditions near concrete barriers, cellulose degradation into isosaccharinic acid was identified, enhancing radionuclide mobility through complex formation. These findings underscore the importance of site-specific sorption and speciation parameters in safety assessment and highlight the need for accurate geochemical modeling to optimize waste placement and ensure long-term disposal safety. The outcomes provide valuable insights for optimizing waste placement and contribute to the development of evidence-based safety strategies for long-term performance assessment. Full article
(This article belongs to the Section Hydrogeology)
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14 pages, 2819 KiB  
Article
First Report of Antibiotic-Resistant Coagulase-Negative Staphylococcus Strains Isolated from Technical Snow on Ski Slopes in Mountain Areas
by Klaudia Stankiewicz and Anna Lenart-Boroń
Water 2025, 17(2), 185; https://doi.org/10.3390/w17020185 - 10 Jan 2025
Abstract
Coagulase-negative staphylococci form a heterogeneous group defined solely by the lack of coagulase. Initially considered non-pathogenic, they are now known to be opportunistic pathogens of increasing importance. This study was conducted to examine the prevalence of Staphylococcus spp., their taxonomic diversity, antibiotic resistance [...] Read more.
Coagulase-negative staphylococci form a heterogeneous group defined solely by the lack of coagulase. Initially considered non-pathogenic, they are now known to be opportunistic pathogens of increasing importance. This study was conducted to examine the prevalence of Staphylococcus spp., their taxonomic diversity, antibiotic resistance patterns and genetic determinants of antibiotic resistance in the water resources used within the technical snow production process. The types of samples included (1) river water at intakes where water is drawn for snowmaking, (2) water stored in technical reservoirs, from which it is pumped into the snowmaking systems, (3) and technical snowmelt water. The study was conducted in the catchments of five rivers: Białka, Biały Dunajec, Raba and Wisła in Poland, and Studený Potok in Slovakia. Staphylococcus spp. was detected in all types of samples: in 17% of river water, 25% of reservoir-stored water and in 60% of technical snowmelt water. All staphylococci were coagulase-negative (CoNS) and belonged to 10 species, with S. epidermidis being the most prevalent in river water, S. warneri and S. pasteuri in reservoir-stored water and S. haemolyticus in snowmelt water. The highest resistance rates to erythromycin and macrolide/lincosamid/streptogramin b (MLSb) types of resistance were detected in all types of samples, accompanied by the erythromycin efflux pump-determining msrA gene as the most frequent genetic determinant of antibiotic resistance. This study is the first report of the presence of antibiotic-resistant, including multidrug-resistant, CoNS carrying more than one gene determining antibiotic resistance in technical snow in the mountain areas of the Central European countries. Full article
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23 pages, 7851 KiB  
Article
A Water Quality Prediction Model Based on Modal Decomposition and Hybrid Deep Learning Models
by Shuo Zhao, Ruru Liu, Yahui Liu, Tao Zeng, Chunpeng Chen and Liping Xu
Water 2025, 17(2), 184; https://doi.org/10.3390/w17020184 - 10 Jan 2025
Abstract
When the total nitrogen content in water sources exceeds the standard, it can promote the rapid proliferation of algae and other plankton, leading to eutrophication of the water body and also causing damage to the ecological environment of the water source area. Therefore, [...] Read more.
When the total nitrogen content in water sources exceeds the standard, it can promote the rapid proliferation of algae and other plankton, leading to eutrophication of the water body and also causing damage to the ecological environment of the water source area. Therefore, making timely and accurate predictions of water quality at the source is of vital importance. Since water quality data exhibit non-stationary characteristics, predicting them is quite challenging. This study proposes a novel hybrid deep learning model based on modal decomposition, ERSCB (EMD-RBMO-SVMD-CNN-BiGRU), to enhance the accuracy of water quality forecasting. The model first employs Empirical Mode Decomposition (EMD) technology to decompose the original water quality data. Subsequently, it quantifies the complexity of the subsequences obtained from EMD using Sample Entropy (SE) and further decomposes the most complex subsequences using Sequential Variational Mode Decomposition (SVMD). To address the matter of selecting balanced parameters in SVMD, this study introduces the Red-Billed Blue Magpie Optimization (RBMO) algorithm to optimize the hyperparameters of SVMD. On this basis, a forecasting model is constructed by integrating Convolutional Neural Networks (CNN) and Bidirectional Gated Recurrent Unit (BiGRU) networks. The experimental results show that, compared to existing water quality prediction models, the ERSCB model has an improved prediction accuracy of 4.0% and 3.1% for the KaShi River and GongNaiSi River areas, respectively. Full article
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17 pages, 5110 KiB  
Article
A Laboratory Investigation into the Effect of Coarse-Grained Layer Mixing with Fine Particles on the Water Storage Capacity of a Capillary Barrier Cover
by Chong Sun, Junjie Yang, Qiang Liu, Yalei Wu and Jiali Miao
Water 2025, 17(2), 183; https://doi.org/10.3390/w17020183 - 10 Jan 2025
Abstract
A capillary barrier cover (CBC) is a geotechnical structure which a coarse-grained soil layer covered by a fine-grained soil layer. A CBC can retain downward water infiltration, increase water storage capacity and lateral diversion, and prevent capillary rise. Geotextiles are usually set up [...] Read more.
A capillary barrier cover (CBC) is a geotechnical structure which a coarse-grained soil layer covered by a fine-grained soil layer. A CBC can retain downward water infiltration, increase water storage capacity and lateral diversion, and prevent capillary rise. Geotextiles are usually set up as isolation layers between fine-grained and coarse-grained layers to prevent fine particles entering the coarse-grained layer, resulting in a decrease in downward water infiltration and water storage capacity. However, crustal stress, farming, animal, plant activities, and other factors may cause damage to the isolation layer. At present, there is no reliable and accurate method to determine the location and degree of damage to the isolation layer. The existing methods search for the damage location by excavating the whole fine layer, which incurs high maintenance costs. If the damaged position of the CBC isolation layer can be accurately obtained, it can reduce maintenance costs. Therefore, this study investigated the influence of a coarse-grained layer mixed with different particle sizes and proportions of fine particles on water storage capacity through laboratory soil column experiments. The results are as follows: (1) Fine particle mixing into the coarse-grained layer will reduce water storage capacity, and there is a worse admixture ratio that minimizes water storage capacity. (2) The CBC enhances the fine-grained layer volumetric water content (VWC), but the enhancement degree decreases as the distance from the fine–coarse interface increases. (3) A method has been proposed to determine the location and degree of damage to the isolation layer. When the VWC at the fine–coarse interface reaches a stable level during breakthrough, the CBC effect exists, the higher the VWC at the fine–coarse interface, the stronger the CBC; when the VWC at the fine–coarse interface is unstable during breakthrough, the CBC effect disappears, and the median diameter of the fine particles mixed into the coarse-grained layer is finer than or equal to the fine-grained particles’ median diameter. Full article
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12 pages, 635 KiB  
Article
Impact of Land Use Change on Lake Pollution Dynamics: A Case Study of Sapanca Lake, Turkey
by Serkan Ozdemir, Ahmet Celebi, Gulgun Dede, Mohsen Maghrebi and Ali Danandeh Mehr
Water 2025, 17(2), 182; https://doi.org/10.3390/w17020182 - 10 Jan 2025
Abstract
Modeling non-point source pollution dynamics in inland lake basins is essential for safeguarding water quality, maintaining ecosystem integrity, protecting public health, and advancing long-term environmental sustainability. This study explores non-point pollution dynamics in the Sapanca Lake basin, Turkey, in association with the basin’s [...] Read more.
Modeling non-point source pollution dynamics in inland lake basins is essential for safeguarding water quality, maintaining ecosystem integrity, protecting public health, and advancing long-term environmental sustainability. This study explores non-point pollution dynamics in the Sapanca Lake basin, Turkey, in association with the basin’s land use, land cover, hydrology, pollutant sources, and water quality parameters. The required data were gathered via a three-year monitoring program, which was carried out at 12 sampling stations around the lake, as well as using the collecting field measurements and GIS databases. Stepwise multiple regression analysis was employed to determine the best relation between non-point pollutants and land features. The results showed that urbanization and population density have significant correlations with the total nitrogen (TN) and total phosphorus (TP) in the study areas. Rivers crossing pristine areas, such as forests and uncultivated lands, demonstrated better water quality, thereby positively contributing to the lake ecosystem conservation. The highest nutrient loads were observed in streams that flow through highly urbanized sub-basins, followed by predominantly agricultural areas. This is likely due to runoff from urban environments, leaching from cultivated land, and contributions from livestock and tourism facilities. Conversely, densely forested regions exhibited the lowest levels of nutrient loads, highlighting their capacity for nutrient retention. The peak levels of non-point source pollution (TN = 5.22 mg/L and TP = 0.53 mg/L) were recorded in catchments with the highest degree of urbanization, whereas the lowest values (TN = 0.28 mg/L and TP = 0.04 mg/L) were found in the least urbanized areas. These findings emphasize that nutrients primarily impact water quality because of increasing urban and agricultural activities, while forested land plays a vital role in preserving lake water quality. To ensure sustainable water quality in lake basins, it is essential to strike a careful balance between protective measures and utilization policies, prioritizing conservation efforts. Full article
28 pages, 3318 KiB  
Review
Importance of Geographic Information System (GIS) Application to Reduce the Impact of Flood Disasters in Malaysia: A Meta-Analysis
by Adam Narashman Leeonis, Minhaz Farid Ahmed, Mazlin Bin Mokhtar, Bijay Halder, Chen Kim Lim, Nuriah Abd Majid and Miklas Scholz
Water 2025, 17(2), 181; https://doi.org/10.3390/w17020181 - 10 Jan 2025
Abstract
Malaysia can accurately analyse flood patterns and susceptible forecast areas and allocate resources as efficiently as possible by leveraging geographic information systems (GIS). Authorities can execute data-driven plans for robust flood control and quick catastrophe response because of this technology. However, in Malaysia, [...] Read more.
Malaysia can accurately analyse flood patterns and susceptible forecast areas and allocate resources as efficiently as possible by leveraging geographic information systems (GIS). Authorities can execute data-driven plans for robust flood control and quick catastrophe response because of this technology. However, in Malaysia, public authorities adequately apply GIS, researchers often limit the use of GIS applications to study natural disasters and communities find GIS challenging to learn and adopt. By producing flood risk mapping using GIS applications that make it easy for the communities to understand the situation, the government and communities can implement programs to mitigate the impacts of natural hazards. Reviewing the available literature on the use of GIS applications in assessing natural hazards, this study found that GIS applications effectively provide flood risk mapping and positively impact natural disaster management to ensure that the worst impacts of natural hazards can be avoided. Moreover, this study revealed the importance of GIS applications and technologies in managing natural hazards in communities to make them better prepared for disaster management. Based on the scientific research, 12 articles were identified to analyse flood management activities in Malaysia. Therefore, the government and relevant agencies should take advantage of the appropriate use of GIS in managing natural disasters and educate the population about applying GIS so that present and future generations can gain this knowledge earlier and use it better in mitigating disaster risks. Full article
(This article belongs to the Special Issue Advances in Crisis and Risk Management of Extreme Floods)
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18 pages, 1400 KiB  
Review
A Multilevel Risk Assessment Framework for Nanoplastics in Aquatic Ecosystems
by Cátia Venâncio and Miguel Oliveira
Water 2025, 17(2), 180; https://doi.org/10.3390/w17020180 - 10 Jan 2025
Abstract
To date, the assessment of risks related to nanoplastics (NPLs) has been incipient. Attempts to establish safety levels to support decisions regarding restrictions on the use or reuse of materials derived from petrochemicals are critical, but the complexity of datasets makes it difficult [...] Read more.
To date, the assessment of risks related to nanoplastics (NPLs) has been incipient. Attempts to establish safety levels to support decisions regarding restrictions on the use or reuse of materials derived from petrochemicals are critical, but the complexity of datasets makes it difficult to communicate potential NPLs-related environmental risks. Therefore, it seems essential to reduce the relevant data to a factor/number that makes it easier to clarify whether there is a risk and, above all, easily report relevant information to legislators so that prohibition, reductions, and/or readjustments to monitoring programs can be implemented accordingly. Accordingly, this study aimed to propose an improved and tiered risk assessment for NPLs following the NORMAN network, which may be outlined as follows: (i) conducting screenings to assess the risk level through deterministic methodologies (involving the collection of effective concentrations or, in their absence, the no-effect or lowest-effect concentrations, also known as NOEC and LOEC, respectively); (ii) comparing exceedance levels of risk values obtained previously in relation to predicted non-environmental effective concentrations (PNECs); and (iii) ranking the different NPL types based on prioritization indeces to facilitate future decision-making. Of a total of six polymers for which data are available, it was only possible to deliver prioritization indices for three (two freshwater and one saltwater) due to the lack of PNEC or predicted environmental concentrations (PECs). The majority of the research on this topic is focused on PS. PS is classified as a high-priority polymer, since its estimated prioritization index was ≥65 (the base value is 1). Furthermore, in freshwater, PE was also indicated to be a priority polymer (with a prioritization index exceeding 1000). It should be noted that for other widely used polymers (such as PMMA or PVC), there is insufficient data. It is therefore clear that current management and control measures for products containing PS and PE must be reconsidered to reduce NPLs’ environmental impacts. Full article
(This article belongs to the Special Issue Impact of Microplastics on Aquatic Ecosystems)
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16 pages, 4247 KiB  
Article
Removal of TP, COD, and NH4+-N in Simulated Slaughtering Wastewater by Two Kinds of Immobilized Microalgal Spheres
by Wei Xu, Xiaoping Zhang, Guichang Zhang and Xin Zhang
Water 2025, 17(2), 179; https://doi.org/10.3390/w17020179 - 10 Jan 2025
Abstract
The treatment of wastewater using microalgae is regarded as a green and potential technology. However, its engineering application has been largely hindered because of the limitation of microalgae separation and harvesting. Therefore, immobilization technology has been widely used to embed microalgae for wastewater [...] Read more.
The treatment of wastewater using microalgae is regarded as a green and potential technology. However, its engineering application has been largely hindered because of the limitation of microalgae separation and harvesting. Therefore, immobilization technology has been widely used to embed microalgae for wastewater treatment. In this paper, sodium alginate (SA) and polyvinyl alcohol (PVA) as the common immobilized carriers were used to immobilize ankistrodesmus falcatus for simulated slaughtering wastewater (SSW) treatment. The experimental results of the mass transfer and adsorption of immobilized carriers were found to show that the mass transfer of SA-SiO2 gel balls (SS-GB) was better than PVA-SA gel balls (PS-GB) and that the adsorption of PS-GB was better than SS-GB. When immobilizing microalgae with the two kinds of carriers, it was found that SA-SiO2 microalgal spheres (SS-MS) were better than PVA-SA microalgal spheres (PS-MS) for the maintenance of microalgal cell activity and that PS-MS were better than SS-MS for the resistance to biodegradation. This is because the carrier of PS-MS had a thick shell and dense structure, while the carrier of SS-MS had a thin shell and loose structure. The results of SSW treatment by PS-MS and SS-MS were found to show that the total phosphorus (TP) removal rates of PS-MS and SS-MS were 90.31% and 86.60%, respectively. This indicates that the TP removal effect of PS-MS was superior to that of SS-MS. The adsorption kinetics simulation showed that the adsorption of TP onto PS-GB was controlled by chemisorption and that the adsorption of TP onto SS-GB was controlled by physical adsorption. The chemical oxygen demand (COD) and ammonium nitrogen (NH4+-N) removal of PS-MS were 9.30% and 10.70%, respectively, and the COD and NH4+-N removal of SS-MS were 54.60% and 62.08%, respectively. This indicates that the COD and NH4+-N removal effect of SS-MS were superior to PS-MS. This is the result of the combined action of the degradation by microalgal cells and adsorption by the carrier. Full article
(This article belongs to the Section Wastewater Treatment and Reuse)
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16 pages, 2306 KiB  
Article
Optimizing Irrigation Regimes for Peanuts in Water-Scarce Regions: A Case Study in Western Liaoning, China
by Siyuan Zhao, Xinhao Du, Jing Chen, Dan Chen, Zhaohui Luo, Bo Bi, Haoran Liu, Lan Lin and Huanghuang Wei
Water 2025, 17(2), 178; https://doi.org/10.3390/w17020178 - 10 Jan 2025
Abstract
Scientific irrigation scheduling is crucial for conserving agricultural water resources, as excessive irrigation diminishes crop yield and imprecise water application can equally reduce water use efficiency (WUE). In Western Liaoning Province, China, where water scarcity is critical, traditional irrigation regimes are commonly used [...] Read more.
Scientific irrigation scheduling is crucial for conserving agricultural water resources, as excessive irrigation diminishes crop yield and imprecise water application can equally reduce water use efficiency (WUE). In Western Liaoning Province, China, where water scarcity is critical, traditional irrigation regimes are commonly used for peanut cultivation, with local farmers applying water without considering actual crop water demands, thereby reducing water efficiency and yield. In this study, field experiments on peanuts were conducted from May to October during 2021 and 2022 in Heishan County, Western Liaoning Province, China. Four irrigation regime treatments for micro-sprinkler irrigation, with different lower limits of soil water content, were applied: T1 (55% field capacity), T2 (65% field capacity), T3 (75% field capacity), and T4 (85% field capacity). The plant height, stem thickness, root length, dry matter weight, yield, WUE, and net return were measured. Different irrigation regimes had significant effects on peanut growth. The yield was highest in the T3 treatment in 2021 at 5574 kg·hm−2. Moderate irrigation could improve the yield, but it was difficult to simultaneously achieve a high WUE. The WUE of the T3 treatment was 5% lower than that of the T2 treatment in 2022, where the WUE was the highest at 1.62 kg·m−3. The highest net return was observed in the T3 treatment at 27,307 yuan·hm−2. The T3 treatment, with the highest similarity degree of 0.83 as determined with the entropy value and TOPSIS method, was evaluated as the optimal irrigation regime. This regime not only exhibited a favorable balance of water use efficiency and yield but also maximized economic benefits, making it a recommendable practice for local peanut irrigation. Full article
(This article belongs to the Special Issue Advances in Agricultural Irrigation Management and Technology)
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18 pages, 10356 KiB  
Article
Automatic Flood Monitoring Method with SAR and Optical Data Using Google Earth Engine
by Xiaoran Peng, Shengbo Chen, Zhengwei Miao, Yucheng Xu, Mengying Ye and Peng Lu
Water 2025, 17(2), 177; https://doi.org/10.3390/w17020177 - 10 Jan 2025
Abstract
Accurate and near-real-time flood monitoring is crucial for effective post-disaster relief efforts. Although extensive research has been conducted on flood classification, efficiently and automatically processing multi-source imagery to generate reliable flood inundation maps remains challenging. In this study, a new automatic flood monitoring [...] Read more.
Accurate and near-real-time flood monitoring is crucial for effective post-disaster relief efforts. Although extensive research has been conducted on flood classification, efficiently and automatically processing multi-source imagery to generate reliable flood inundation maps remains challenging. In this study, a new automatic flood monitoring method, utilizing optical and Synthetic Aperture Radar (SAR) imagery, was developed based on the Google Earth Engine (GEE) cloud platform. The Normalized Difference Flood Vegetation Index (NDFVI) was innovatively combined with the Edge Otsu segmentation method, utilizing SAR imagery, to enhance the initial accuracy of flood area mapping. To more effectively distinguish flood areas from non-seasonal water bodies, such as lakes, rivers, and reservoirs, pre-flood Landsat-8 imagery was analyzed. Non-seasonal water bodies were classified using multi-index methods and water body probability distributions, thereby further enhancing the accuracy of flood mapping. The method was applied to the catastrophic floods in Poyang Lake, Jiangxi Province, in 2020, and East Dongting Lake, Hunan Province, China, in 2024. The results demonstrated classification accuracies of 92.6% and 97.2% for flood inundation mapping during the Poyang Lake and East Dongting Lake events, respectively. This method offers efficient and precise information support to decision-makers and emergency responders, thereby fully demonstrating its substantial potential for practical applications. Full article
(This article belongs to the Special Issue Applications of Remote Sensing and Modeling in Hydrological Systems)
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14 pages, 8366 KiB  
Article
Digital Elevation Model Extraction and Correction of Hilly River Channel Network in Pi-Shi-Hang Irrigation District, China
by Longzhu Guo and Yiming Huang
Water 2025, 17(2), 176; https://doi.org/10.3390/w17020176 - 10 Jan 2025
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Abstract
This research focuses on river and canal systems extraction in hilly irrigation areas. It aims to improve extraction precision and correct the DEM. Given the significance and challenges, the hilly area of the Pi-Shi-Hang Irrigation District is selected as the study area. The [...] Read more.
This research focuses on river and canal systems extraction in hilly irrigation areas. It aims to improve extraction precision and correct the DEM. Given the significance and challenges, the hilly area of the Pi-Shi-Hang Irrigation District is selected as the study area. The study integrates water systems with channels uses with 12.5 m DEM data for 2018 from Pi-Shi-Hang Irrigation District. The key working areas are determined through slope analysis. Based on ArcGIS 10.8.2, the elevation of the raster at the inflection points in the problem area is lowered by 3 m. ArcSWAT 2012_10.8.26 is used to construct a complete water network structure and to search for an appropriate threshold for the water system in the Pi-Shi-Hang Irrigation District. It is based on integrating three key features: water system density, tributary development coefficient, and water system connectivity. Research results derived in this paper show that the chosen thresholds of 50 hectares for the Yangtze River system and 150–200 hectares for the Huai River system can more accurately reflect the characteristics of the water system in this region. Moreover, the corrected and optimized DEM has remarkably enhanced the accuracy of extracting the river channel network in hilly areas, thus supplying more precise basic data for related field applications. Full article
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19 pages, 9935 KiB  
Article
Biochar-Based Solutions for Urban Artificial Landscape Water Bodies: Mitigating Eutrophication and Enhancing Visual Aesthetics
by Ran Jiao, Zhiqiang Zhou, Mo Wang and Liang Dong
Water 2025, 17(2), 175; https://doi.org/10.3390/w17020175 - 10 Jan 2025
Viewed by 117
Abstract
This study examines the efficacy of biochar in improving water quality in urban artificial landscape water bodies. Three biochar types—wood biochar, coconut shell biochar, and apricot kernel biochar—were systematically evaluated, along with the purification effects of varying biochar dosages on landscape water. Water [...] Read more.
This study examines the efficacy of biochar in improving water quality in urban artificial landscape water bodies. Three biochar types—wood biochar, coconut shell biochar, and apricot kernel biochar—were systematically evaluated, along with the purification effects of varying biochar dosages on landscape water. Water quality parameters were quantified using a multiparameter water quality meter, while the enhancement of visual aesthetics was validated through online questionnaires distributed to citizens. The findings include the following: All biochar types significantly reduced eutrophication indices and enhanced visual quality metrics, with coconut shell biochar demonstrating the most pronounced effects. The purification effect correlates with initial water quality and biochar dosage. Water bodies with poorer initial quality tend to show better purification results. While optimal biochar dosage improves water quality parameters, excessive application leads to decreased performance and potential water quality deterioration. Questionnaire analysis of visual preferences for the purified water showed that among biochar types, coconut shell biochar was most preferred (53.2%), followed by apricot kernel biochar (22.8%) and wood biochar (17.2%), while untreated water received the lowest preference (6.8%). When evaluating coconut shell biochar dosages, the 10 g/L treatment achieved the highest preference (67.4%), followed by 5 g/L (18.2%), while both the 15 g/L treatment and untreated water received notably lower preferences (7.1% and 7.3%, respectively). These findings highlight biochar as a promising tool for enhancing both the ecological and aesthetic qualities of urban water bodies, provided its application is carefully tailored to variable environmental conditions. Full article
(This article belongs to the Section Urban Water Management)
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17 pages, 846 KiB  
Article
Coastal Bathing Water Quality in Portugal and Poland: Students’ Perspectives of Its Importance
by Aldona Dobrzycka-Krahel and Maria Leonor Fidalgo
Water 2025, 17(2), 174; https://doi.org/10.3390/w17020174 - 10 Jan 2025
Viewed by 68
Abstract
Coastal bathing waters are leading tourist destinations, mainly during holiday periods. Therefore, the quality of bathing waters is of key importance to tourists. In 2006, the European Union (EU) adopted the Bathing Water Directive (BWD). EU Member States are required to analyze the [...] Read more.
Coastal bathing waters are leading tourist destinations, mainly during holiday periods. Therefore, the quality of bathing waters is of key importance to tourists. In 2006, the European Union (EU) adopted the Bathing Water Directive (BWD). EU Member States are required to analyze the status of their bathing waters, the quality of which is determined by the presence or absence of microbial contaminants (Escherichia coli and enterococci). This study presents the quality of coastal bathing waters in Portugal and Poland during the 3-year period from 2020 to 2022. The difference in the bathing water quality of the two countries—excellent in Portugal versus worse in Poland—is caused by their contrasting management and sampling practices and differing geographical and environmental conditions (in Portugal, warm, open sea, and in Poland, a temperate, semi-enclosed sea that is almost surrounded by land and is exposed to urban wastewater discharge). Additionally, the results of a questionnaire showed that ecological awareness and responses are well developed in Portuguese and Polish students regardless of the different status of their bathing waters. To the best of the authors’ knowledge, this study is among the first to analyze the relationships between water pollution and students’ ecological awareness and opinions on tourism. The results provide valuable information that policymakers, tourist entities, and educational institutions can use to develop more efficient management strategies for the coastal bathing waters in both countries. Full article
(This article belongs to the Special Issue Aquatic Ecosystem: Problems and Benefits—2nd Edition)
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22 pages, 9464 KiB  
Article
Elucidating the Electrochemical Corrosion of a Water Pump Impeller in an Industrial Cooling System with Zero Liquid Discharge
by Mina Mousavi Jarrahi, Ehsan Khajavian, Amir Hossein Noorbakhsh Nezhad, Ehsan Mohammadi Zahrani and Akram Alfantazi
Water 2025, 17(2), 173; https://doi.org/10.3390/w17020173 - 10 Jan 2025
Viewed by 101
Abstract
The electrochemical corrosion of a single-suction centrifugal water pump impeller made of gray cast iron operating at 85 °C was investigated in two industrial water media, i.e., groundwater extracted from a borehole and treated wastewater. Open circuit potential (OCP) measurement plus potentiodynamic polarization [...] Read more.
The electrochemical corrosion of a single-suction centrifugal water pump impeller made of gray cast iron operating at 85 °C was investigated in two industrial water media, i.e., groundwater extracted from a borehole and treated wastewater. Open circuit potential (OCP) measurement plus potentiodynamic polarization (PDP) and electrochemical impedance spectroscopy (EIS) techniques elucidated the electrochemical corrosion performance and inductively coupled plasma-optical emission spectroscopy (ICP-OES) characterized the water samples. The retired and brand-new impellers were studied using scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDX), and visual and metallographic examinations. Impeller trailing edges were vulnerable to corrosion damage due to increased total fluid pressure, velocity, and temperature. The groundwater was more contaminated with Ca, Mg, Na, Si, and S elements and possessed higher conductivity, pH, and suspended solids than the treated wastewater. The impeller was more susceptible to graphitic corrosion in the groundwater due to emerging microgalvanic cells. A kinetic control electrochemical mechanism was elucidated as the corrosion rate-controlling step in the wastewater. A mixed kinetic and diffusion control mechanism was predominant in the groundwater because a short Warburg impedance element emerged. This study showcased the significance of integrated industrial water management and treatment strategies to protect pumps’ integrity and uptime in critical industrial units implementing a zero-liquid discharge program. Full article
(This article belongs to the Special Issue Water Engineering Safety and Management)
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18 pages, 7811 KiB  
Article
Study on Slope Stability of Paleo-Clay Strength Degradation Under Soaking and Wet–Dry Cycles
by Qian Chen, Echuan Yan, Shaoping Huang, Nuo Chen, Hewei Xu and Fengyang Chen
Water 2025, 17(2), 172; https://doi.org/10.3390/w17020172 - 10 Jan 2025
Viewed by 73
Abstract
Due to Paleo-clay’s unique properties and widespread distribution throughout China, it is essential in geotechnical engineering. Rainfall frequently causes the deformation of Paleo-clay slopes, making slope instability prediction crucial for disaster prevention. This study explored Paleo-clay’s strength degradation and slope stability under soaking [...] Read more.
Due to Paleo-clay’s unique properties and widespread distribution throughout China, it is essential in geotechnical engineering. Rainfall frequently causes the deformation of Paleo-clay slopes, making slope instability prediction crucial for disaster prevention. This study explored Paleo-clay’s strength degradation and slope stability under soaking and wet–dry cycles. Using Mohr–Coulomb failure envelopes from experiments, curve fitting was used to find the patterns of Paleo-clay strength degradation. Finite element simulations and the strength discounting method were used to analyze the stability and deformation of Paleo-clay slopes. The results indicate that wet–dry cycles impact them more than soaking. Paleo-clay’s cohesion decreases exponentially as the number of wet–dry cycles and soaking times rise, but the internal friction angle changes very little. After 10 wet–dry cycles and 24 days of soaking, iron-bearing clay’s cohesion decreased to 17% and 44% and reticular clay’s to 32% and 48%. Based on the study area characteristics, three slope types were constructed. Their stability exhibited exponential decay. Under soaking, stability remained above 1.4; under wet–dry cycles, type I and II stability fell below 1.0, leading to deformation and failure. All types showed traction landslides with sliding zones transitioning from deep to shallow. Practical engineering should focus on the shallow failures of Paleo-clay slopes. Full article
(This article belongs to the Special Issue Water-Related Geoenvironmental Issues, 2nd Edition)
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24 pages, 3758 KiB  
Review
Technical Analysis and Application Prospects of Magnetic Source Transient Electromagnetic Coil Devices in Hydrogeological Survey of Mining Area
by Yang Yang, Fei Yang, Bo Wang, Wangping Qian, Ying Wang and Yuanbin Zuo
Water 2025, 17(2), 171; https://doi.org/10.3390/w17020171 - 10 Jan 2025
Viewed by 129
Abstract
The transient electromagnetic method (TEM) has a wide range of applications in the hydrogeological exploration of mining engineering. This method is highly sensitive to groundwater responses and provides reliable data for the prevention of water-related disasters, such as sudden water surges and gushes. [...] Read more.
The transient electromagnetic method (TEM) has a wide range of applications in the hydrogeological exploration of mining engineering. This method is highly sensitive to groundwater responses and provides reliable data for the prevention of water-related disasters, such as sudden water surges and gushes. However, there are currently a lack of comprehensive and systematic analyses and summaries regarding the characteristics of magnetic source transient electromagnetic coil devices. Based on the fixed characteristics of the field source, this paper categorizes magnetic source transient electromagnetic coil devices into fixed-source devices and moving-source devices. It provides an in-depth introduction and analysis of the working principles, technical characteristics, existing applications, and development trends of these two types of devices. This study provides important references for the selection and application of magnetic source transient electromagnetic coil devices. In the future, the development of magnetic source transient electromagnetic devices will focus on deeper measurement depths, higher lateral resolution, non-contact coupling, and efficient detection, moving towards multifunctionality, automation, and intelligence. This paper can provide a technical reference for the selection of magnetic source transient electromagnetic coil devices and their application in hydrogeological exploration of mining engineering. Full article
(This article belongs to the Special Issue Engineering Hydrogeology Research Related to Mining Activities)
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22 pages, 981 KiB  
Review
Use, Potential, Needs, and Limits of AI in Wastewater Treatment Applications
by Andrea G. Capodaglio and Arianna Callegari
Water 2025, 17(2), 170; https://doi.org/10.3390/w17020170 - 10 Jan 2025
Viewed by 155
Abstract
Artificial intelligence (AI) uses highly powerful computers to mimic human intelligent behavior; it is a major research hotspot in science and technology, with an increasing number of applications to a wider range of fields, including complex process supervision and control. Wastewater treatment is [...] Read more.
Artificial intelligence (AI) uses highly powerful computers to mimic human intelligent behavior; it is a major research hotspot in science and technology, with an increasing number of applications to a wider range of fields, including complex process supervision and control. Wastewater treatment is an example of a complex process involving many uncertainties and external factors to achieve a final product with specific requisites (effluents with prescribed quality). Reducing process energy consumption, greenhouse gas emissions, and resources recovery are additional requirements of these facilities’ operation. AI could extend the purpose and the expected results of previously adopted tools and present operational approaches by leveraging superior simulation, prediction, control, and adaptation capabilities. This paper reviews current AI research in the wastewater field and discusses present achievements and potentials. So far, almost all applications in the sector involve predictive studies, often at a small scale or with limited data use. Frontline research aimed at the creation of AI-supported digital twins of real systems is being conducted, with few encouraging but still limited applications. This paper aims at identifying and discussing key barriers to wider AI adoption in the field, which include laborious instrumentation maintenance, lack of process expertise in the design of current software, instability of control loops, and insufficient incentives for resource efficiency achievement. Full article
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13 pages, 4124 KiB  
Article
Driving Factors and Variability of Cyanobacterial Blooms in Qionghai Lake, Yunnan–Guizhou Plateau, China
by Yanzhen Dong, Zebin Tian, Xiaoyan Li, Dayong Xu and Binghui Zheng
Water 2025, 17(2), 169; https://doi.org/10.3390/w17020169 - 10 Jan 2025
Viewed by 201
Abstract
Qionghai Lake is an important freshwater source in the Yunnan–Guizhou Plateau. However, cyanobacterial blooms have been observed recently in Qionghai Lake, but their formation mechanism and control management are not well understood. Herein, phytoplankton, zooplankton, eutrophication, nutrients, and biochemical indices were measured in [...] Read more.
Qionghai Lake is an important freshwater source in the Yunnan–Guizhou Plateau. However, cyanobacterial blooms have been observed recently in Qionghai Lake, but their formation mechanism and control management are not well understood. Herein, phytoplankton, zooplankton, eutrophication, nutrients, and biochemical indices were measured in Qionghai Lake from May 2022 to April 2023. The results showed that cyanobacterial blooms in Qionghai Lake predominated in Anabaena sp. with a density of 1.11 × 107–18.87 × 107 cells/L. Anabaena blooms started in the northwestern area of Qionghai Lake in November 2022 and then expanded to the entire lake until it peaked and subsided in February 2023. Protozoa dominated in zooplankton while having no significant relationship with Anabaena blooms in Qionghai Lake. The trophic level index and chlorophyll a showed similar spatiotemporal trends with Anabaena sp. density, and water quality in the northwest of the Qionghai Lake was worse than in other parts. Total nitrogen (TN) and total phosphorus (TP) were 0.41–0.54 and 0.021–0.045 mg/L from November 2022 to February 2023. TN and TP were positively correlated with Anabaena sp. density, but TP was the most significant environmental factor affecting Anabaena bloom in Qionghai Lake. These findings might provide essential information for improving bloom control and water quality remediation in Qionghai Lake. Full article
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19 pages, 7132 KiB  
Article
Green Synthesis of Sustainable and Cost-Effective TiO2-SiO2-Fe2O3 Heterojunction Nanocomposites for Rhodamine B Dye Degradation Under Sunlight
by Sara Oumenoune Tebbi, Abdeltif Amrane, Reguia Boudraa, Jean-Claude Bollinger, Stefano Salvestrini, Muhammad Imran Kanjal, Ammar Tiri, Lazhar Belkhiri, Maymounah N. Alharthi and Lotfi Mouni
Water 2025, 17(2), 168; https://doi.org/10.3390/w17020168 - 10 Jan 2025
Viewed by 189
Abstract
TiO2-SiO2-Fe2O3 heterojunction using the ceramic technique was used in this study to investigate its effectiveness as a photocatalyst for Rhodamine B (RhB) dye degradation. Structural, optical, and morphological characterizations of the synthesized materials were carried out [...] Read more.
TiO2-SiO2-Fe2O3 heterojunction using the ceramic technique was used in this study to investigate its effectiveness as a photocatalyst for Rhodamine B (RhB) dye degradation. Structural, optical, and morphological characterizations of the synthesized materials were carried out by X-ray diffraction (XRD), photoluminescence analysis (PL), scanning electron microscopy (SEM-EDS), and diffuse reflectance spectroscopy (DRS) to calculate the gap energy. In addition, a degradation rate of around 97% was obtained at a pH of 8, an initial RhB concentration of 10 mg·L−1, a TS-1F semiconductor dosage of 1 g·L−1, and a reaction time of 210 min. The ability of photocatalysis to degrade RhB at different ratios, pH, and with/without H2O2 in aqueous media was evaluated under UV light, visible light (250 W), and sunlight. When it comes to the degradation of RhB under visible light (250 W) and sunlight, respectively, the influence of the np junction showed promising results for the degradation of RhB. In contrast, there was no discernible photocatalytic activity under UV light, which proves that the absorbance switched from UV to visible, demonstrating the decrease in the band gap energy. Additionally, an analysis of the procedure’s cost-effectiveness and reusability through an economic study revealed that the synthesized material was interesting in terms of both cost and sustainability. Full article
(This article belongs to the Special Issue Water Treatment Using Nanomaterials and Nanotechnology)
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23 pages, 11153 KiB  
Article
Landslide Susceptibility Mapping Using an LSTM Model with Feature-Selecting for the Yangtze River Basin in China
by Peng Zuo, Wen Zhao, Wenjun Yan, Jiming Jin, Chaoying Yan, Biqiong Wu, Xiangyu Shao, Weijie Wang, Zeyu Zhou and Jin Wang
Water 2025, 17(2), 167; https://doi.org/10.3390/w17020167 - 10 Jan 2025
Viewed by 179
Abstract
Landslide susceptibility mapping (LSM) is crucial for disaster prevention in large, complex regions characterized by high-dimensional data. This study proposes a Feature-Selecting Long Short-Term Memory (FS-LSTM) framework to enhance LSM accuracy by integrating feature selection techniques with sequence-based modeling. The Mean Decrease Impurity [...] Read more.
Landslide susceptibility mapping (LSM) is crucial for disaster prevention in large, complex regions characterized by high-dimensional data. This study proposes a Feature-Selecting Long Short-Term Memory (FS-LSTM) framework to enhance LSM accuracy by integrating feature selection techniques with sequence-based modeling. The Mean Decrease Impurity (MDI) and Information Gain Ratio (IGR) were used to rank landslide conditioning factors (LCFs), and these rankings structured FS-LSTM inputs to assess the impact of feature ordering on model performance. Feature-ordering experiments demonstrated that structured rankings significantly improve model accuracy compared to randomized inputs. Our model outperformed traditional machine learning algorithms, such as logistic regression and Support Vector Machine, as well as standard deep learning models like CNN and basic LSTM, achieving a score of 0.988. The MDI and IGR rankings consistently identified soil type, elevation, and average annual cumulated rainfall as the most influential LCFs, improving the interpretability of the results. Applied to the Yangtze River Basin, the FS-LSTM framework effectively identified landslide-prone areas, aligning with known geological patterns. These findings highlight the potential of combining feature selection with sequence-sensitive deep learning to enhance the robustness and interpretability of LSM. Future studies could expand this approach to other regions and incorporate real-time monitoring systems for dynamic disaster management. Full article
(This article belongs to the Special Issue Water-Related Landslide Hazard Process and Its Triggering Events)
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16 pages, 1099 KiB  
Review
Efficiency of Graphene Quantum Dots in Water Contaminant Removal: Trends and Future Research Directions
by Juliana P. Rodríguez-Caicedo, Diego R. Joya-Cárdenas, Miguel A. Corona-Rivera, Noé Saldaña-Robles, Cesar E. Damian-Ascencio and Adriana Saldaña-Robles
Water 2025, 17(2), 166; https://doi.org/10.3390/w17020166 - 10 Jan 2025
Viewed by 178
Abstract
This review explores the efficiency and mechanisms of GQDs in removing contaminants from water, emphasizing their potential for environmental applications. GQDs possess unique physicochemical properties, such as a high surface area, tunable photoluminescence, and strong adsorption capacities, which enable the effective removal of [...] Read more.
This review explores the efficiency and mechanisms of GQDs in removing contaminants from water, emphasizing their potential for environmental applications. GQDs possess unique physicochemical properties, such as a high surface area, tunable photoluminescence, and strong adsorption capacities, which enable the effective removal of diverse contaminants, including heavy metals, organic compounds, and dyes. Their electron-hole separation efficiency and functionalizability enhance their reactivity and selectivity. Notable findings include the integration of GQDs into advanced nanocomposites and supramolecular networks, significantly improving their adsorption and catalytic performance. However, challenges such as variability in synthesis methods, stability under environmental conditions, and the environmental impact of GQDs remain. Addressing these limitations and understanding the interaction mechanisms between GQDs and contaminants are critical. Future research should prioritize scalable green synthesis techniques, long-term environmental assessments, and optimized functionalization strategies to establish GQDs as a sustainable solution in water purification technologies. Full article
(This article belongs to the Special Issue The Control of Legacy and Emerging Pollutants in Soil and Water)
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21 pages, 5603 KiB  
Article
Enhancing Groundwater Resource Management in the Milan Urban Area Through a Robust Stratigraphic Framework and Numerical Modeling
by Luca Alberti, Pietro Mazzon, Loris Colombo, Martino Cantone, Matteo Antelmi, Fabio Marelli and Paola Gattinoni
Water 2025, 17(2), 165; https://doi.org/10.3390/w17020165 - 9 Jan 2025
Viewed by 240
Abstract
Groundwater is a critical freshwater resource in Italy’s Po plain, which includes Milan (northern Italy), one of Europe’s most industrialized and urbanized areas. This region relies heavily on groundwater for both industrial and public water supplies. However, the quantity and quality of this [...] Read more.
Groundwater is a critical freshwater resource in Italy’s Po plain, which includes Milan (northern Italy), one of Europe’s most industrialized and urbanized areas. This region relies heavily on groundwater for both industrial and public water supplies. However, the quantity and quality of this resource are vulnerable to both natural and human-induced factors, such as climate change, industrial activities, and changing water use practices. This study investigates and addresses the complex management challenges of groundwater resources of Milan in the framework of the EU directives. A steady-state groundwater flow model was developed as part of the broader project MODEL-MI to aid in the creation of a Water Safety Plan (WSP). This study highlights the importance of accurate stratigraphic data to constructing a reliable hydrogeological conceptual model. The model, calibrated using extensive data, successfully reproduces groundwater flow patterns and will be used both to support decision-making for sustainable groundwater management and to predict future impacts of climate change on water resources. Full article
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22 pages, 8644 KiB  
Article
Enhanced Transport Induced by Tropical Cyclone and River Discharge in Hangzhou Bay
by Hongquan Zhou and Xiaohui Liu
Water 2025, 17(2), 164; https://doi.org/10.3390/w17020164 - 9 Jan 2025
Viewed by 277
Abstract
Sediment transport in Hangzhou Bay and the adjacent Changjiang Estuary is extremely complex due to the bathymetry and hydrodynamic conditions in this region. Using the particle tracing method based on the ROMS model, three-dimensional (3D) passive particle transport in Hangzhou Bay and the [...] Read more.
Sediment transport in Hangzhou Bay and the adjacent Changjiang Estuary is extremely complex due to the bathymetry and hydrodynamic conditions in this region. Using the particle tracing method based on the ROMS model, three-dimensional (3D) passive particle transport in Hangzhou Bay and the Changjiang Estuary was simulated. Ocean temperature, salinity, and circulation patterns before and during Severe Tropical Storm Ampil (2018) were reproduced by the model. The circulation in Hangzhou Bay is significantly influenced by the passing of the storm with an enhanced southeastward surface current. The along-front current offshore of the Changjiang Estuary, accompanied by the Changjiang River plume, is weakened by strong mixing under the storm. The transport of passive particles before and during the storm was also simulated based on the current fields of the model. The results show that the passing of the tropical storm enhances mass exchange in Hangzhou Bay by the storm-induced southeast circulation, while particle transport near the Changjiang Estuary decreases as the estuarine plume is weakened by the intense mixing of strong winds of the storm. Full article
(This article belongs to the Special Issue Hydrodynamics and Sediment Transport in Ocean Engineering)
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14 pages, 2112 KiB  
Article
Performance of Integrated Biofilm-Phytoremediation Process in Reclaiming Water from Domestic Wastewater
by Fairuz Afiqah Buslima, Hassimi Abu Hasan, Jahira Alias, Jaga Sahsiny Jaganathan, Junaidah Buhari, Suriya Vathi Subramanian and Siti Rozaimah Sheikh Abdullah
Water 2025, 17(2), 163; https://doi.org/10.3390/w17020163 - 9 Jan 2025
Viewed by 359
Abstract
The rapid development of the residential and industrial sectors produces a huge amount of treated domestic wastewater. The treated wastewater is discharged and could affect the environment in the long term. Improving the quality of treated domestic wastewater for water reclamation would benefit [...] Read more.
The rapid development of the residential and industrial sectors produces a huge amount of treated domestic wastewater. The treated wastewater is discharged and could affect the environment in the long term. Improving the quality of treated domestic wastewater for water reclamation would benefit both sectors. This study aims to determine the efficiency of the biofilm-phytoremediation integration process in reclaiming domestic wastewater. A cuboid-shaped reactor was filled with 15 L of domestic wastewater, utilizing water hyacinth and a polyethylene carrier as supporting media for the process. The integrated reactor is tested in two phases: the initial adaptation of bacteria with domestic and synthetic wastewater (Phase I) and the integration process of biofilm-phytoremediation, based on the factors of NH3-N concentration and hydraulic retention time (HRT), for 24 to 48 h (Phase II). In Phase II, pollutant removal was observed at varying NH3-N concentrations: C1 (11–13 mg/L), C2 (9–11 mg/L), and C3 (3–5 mg/L). The study’s findings indicate a consistent performance in the first phase, with removal rates for COD and NH3-N ranging between 86.7–100.0% and 79.0–99.6%, respectively. The reactor effectively removed pollutants at varying concentrations of NH3-N, with average removal up to 100% (COD), 99% (NH3-N), and 80% (PO43−). This integrated reactor shows the finest treated water quality outcomes for non-potable water recovery, as well as offers an alternative to resolve water scarcity for use in various sectors. Full article
(This article belongs to the Section Wastewater Treatment and Reuse)
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24 pages, 4223 KiB  
Article
Research on Enhancing Domestic Wastewater Treatment in the Heterotrophic Nitrification–Aerobic Denitrification-Based Anaerobic/Oxic Biofilm System
by Yingbao Wu, Biaoyi Wang, Ziyi Ou, Peiqin Peng, Miaomiao Zhang, Shunan Zhang and Feng Liu
Water 2025, 17(2), 162; https://doi.org/10.3390/w17020162 - 9 Jan 2025
Viewed by 216
Abstract
Traditional wastewater treatment processes still encounter challenges such as the limited treatment efficiency and excessive greenhouse gas emissions, which restrict their application in environmentally sustainable practices. This study developed an A/O biofilm system and assessed the impact of inoculating the system with the [...] Read more.
Traditional wastewater treatment processes still encounter challenges such as the limited treatment efficiency and excessive greenhouse gas emissions, which restrict their application in environmentally sustainable practices. This study developed an A/O biofilm system and assessed the impact of inoculating the system with the heterotrophic nitrification–aerobic denitrification (HN–AD) strain Alcaligenes faecalis WT14 on pollutant removal efficiency and greenhouse gas emissions. A continuous monitoring experiment was conducted over 140 days, comparing the system inoculated with WT14 (the TWT14 system) and the non-inoculated system (the CK system). The results demonstrated that the TWT14 system outperformed the CK system in pollutant removal, with higher NH₄⁺-N, TN, and COD removal efficiencies of 11.22%, 21.96%, and 12.51%, respectively, and the quality of discharge water from TWT14 maintaining compliance with national discharge standards. This improvement underscores the positive impact of inoculation with the WT14 strain on enhancing the pollutant removal performance of the A/O biofilm system. Regarding greenhouse gas emissions, the TWT14 system exhibited a significantly higher N₂O emission flux in the aeration tank compared with the CK system, while CO₂ and CH₄ emissions were predominantly concentrated in the anaerobic tank. Global warming potential (GWP) analysis showed no significant difference in the total average GWP between the two systems. However, the TWT14 system demonstrated a lower GWP per unit of TN removed, highlighting its superior ecological benefits. Environmental factor analysis revealed that the temperature, pH, humidity, and salinity had significant impacts on both pollutant removal efficiency and greenhouse gas emissions. Additionally, microbial community analysis indicated that inoculation with the WT14 strain enhanced microbial diversity and richness within the A/O biofilm system, with Alcaligenes and norank_f_JD30-KF-CM45 playing key roles in nitrogen removal. This study provides valuable insights for optimizing A/O biofilm system design and offers scientific guidance for the sustainable upgrading of wastewater treatment technologies. Full article
(This article belongs to the Special Issue Biological Wastewater Treatment Process and Nutrient Recovery)
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14 pages, 2881 KiB  
Article
An Efficient Photocatalytic Material, rGO-TiO2, That Can Be Industrially Produced: Fabrication and Structural Characterization
by Nan Xiong, Yansen Guo, Yanyan Nie, Yuqing Yao, Zhemian Ying, Wei Zhang, Renduo Liu, Xiaoling Wu, He Zhou, Limin Zhou, Ying Wang, Jian He and Long Yan
Water 2025, 17(2), 161; https://doi.org/10.3390/w17020161 - 9 Jan 2025
Viewed by 288
Abstract
As a well-known photocatalyst, TiO2 still suffers from rapid electron–hole recombination and limited visible light absorption. To overcome these challenges, the combination of graphene and TiO2 has been proposed. However, traditional methods such as ball milling and hydrothermal synthesis face limitations, [...] Read more.
As a well-known photocatalyst, TiO2 still suffers from rapid electron–hole recombination and limited visible light absorption. To overcome these challenges, the combination of graphene and TiO2 has been proposed. However, traditional methods such as ball milling and hydrothermal synthesis face limitations, including high energy consumption and complex procedures. Here, we develop a simple and industrially feasible method to prepare reduced graphene oxide (rGO)-coated TiO2 nanoparticles, referred to as rGO-TiO2 composites. The optimized rGO-TiO2 composites exhibit an enhanced photocatalytic degradation of rhodamine B (RhB) under simulated sunlight conditions, about 99.95% for 4% rGO-TiO2 within 80 min. The first-order reaction rate constant (k) of 4% rGO-TiO2 (0.0867 min−1) is 5.42 times higher than that of nano TiO2 (0.0135 min−1). The key reactive species involved in the degradation process are identified. Additionally, the effects of pH and NaCl concentration on the degradation efficiency of rGO-TiO2 are also investigated. The 4% rGO-TiO2 composite exhibits an excellent photocatalytic activity within the pH range of 3.87–11.89, and the NaCl concentration does not affect its photocatalytic efficiency. After characterization, the enhanced photocatalytic activity is ascribed to the introduction of rGO and the generation of surface oxygen vacancies (OV) and Ti3+ in TiO2 crystals. Full article
(This article belongs to the Special Issue Advanced Nanomaterials for Water and Wastewater Treatment)
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16 pages, 4585 KiB  
Article
Application of Machine Learning to Identify Influential Factors for Fecal Contamination of Shallow Groundwater
by Jianyong Wu, Yanni Cao, Md. Sirajul Islam and Michael Emch
Water 2025, 17(2), 160; https://doi.org/10.3390/w17020160 - 9 Jan 2025
Viewed by 277
Abstract
Understanding influential factors for fecal contamination in groundwater is critical for ensuring water safety and public health. The objective of this study is to identify key factors for fecal contamination of shallow tubewells using machine learning methods. Three methods, including recursive feature elimination [...] Read more.
Understanding influential factors for fecal contamination in groundwater is critical for ensuring water safety and public health. The objective of this study is to identify key factors for fecal contamination of shallow tubewells using machine learning methods. Three methods, including recursive feature elimination (RFE) with XGBoost, Random Forest, and mutual information, were implemented to examine E. coli presence and concentration in 1495 tubewell water samples in Matlab, Bangladesh. For E. coli presence, climatic variables, including average rainfall and temperature over the 30, 15, and 7 days preceding sampling, as well as ambient temperature and rainfall on the sampling day, emerged as critical predictors. Land cover characteristics, such as the percentages of urban and agricultural areas within 100 m of a tubewell, were also significant. For E. coli concentration, land cover characteristics within 100 m, the number of hot and heavy-rain days in the 30 days preceding sampling, average rainfall and temperature in the 3 days preceding sampling, and ambient temperature on the sampling day were identified as key drivers. Random Forest and mutual information yielded results that were more similar to each other than to those of RFE with XGBoost. The findings highlight the interplay between climatic factors, land use, and population density in determining fecal contamination in shallow well water and demonstrate the power of machine learning algorithms in ranking these factors. Full article
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23 pages, 3831 KiB  
Article
Evaluation of Hydraulic Performance of Sewage Pipe Networks
by Peng Li, Yitao Zhang, Peng Zhao, Dongmei Gu and Shaohua Wang
Water 2025, 17(2), 159; https://doi.org/10.3390/w17020159 - 9 Jan 2025
Viewed by 256
Abstract
With the continuous increase in the urbanization rate, the amount of sewage received by the sewage pipe network has also been increasing annually. The phenomenon of high water level operation in sewage pipe networks has emerged in many cities, which seriously affects drainage [...] Read more.
With the continuous increase in the urbanization rate, the amount of sewage received by the sewage pipe network has also been increasing annually. The phenomenon of high water level operation in sewage pipe networks has emerged in many cities, which seriously affects drainage efficiency. Therefore, constructing an effective evaluation method to assess the hydraulic performance of pipe networks operating at high water levels, as well as identifying high-risk pipelines, formulating cost-effective rehabilitation schemes, and evaluating the rehabilitation effects has become necessary to solve this problem. In this study, a sewage pipe network hydraulic performance evaluation method based on flow velocity, pipe fullness, and manhole fullness was established. This method comprehensively considers the instantaneous values and cumulative operation durations of each indicator in the pipeline and, thus, can accurately evaluate the hydraulic performance of the pipe network. This method was applied to the sewage pipe network in City H, and it was found that there existed problems such as low flow velocity, unreasonable pipe diameter, overloading, and high risk of overflow. After the renovation of specific pipeline sections according to the evaluation results, the comprehensive hydraulic performance of the pipe network was significantly improved, with the grade rising from “poor” to “medium +”. This research shows that this evaluation method can accurately assess the hydraulic performance of the current and the renovated sewage pipe network, providing scientific guidance for the renovation and optimization. Full article
(This article belongs to the Special Issue Urban Sewer Systems: Monitoring, Modeling and Management)
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19 pages, 5619 KiB  
Article
Graphitic Carbon Nitride/CeO2 Nanocomposite for Photocatalytic Degradation of Methyl Red
by Khansaa Al-Essa, Ethar M. Al-Essa, Alaa Qarqaz, Suhad Al-Issa, Solhe F. Alshahateet and O’la Al-Fawares
Water 2025, 17(2), 158; https://doi.org/10.3390/w17020158 - 9 Jan 2025
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Abstract
Nanosized ceria (CeO2) and a graphitic carbon nitride-loaded ceria (CeO2/GCN) nanocomposite were synthesized using a straightforward and efficient method and characterized by XRD, FTIR, SEM, TEM, TGA, and BET analyses. These techniques confirmed that CeO2 was effectively supported [...] Read more.
Nanosized ceria (CeO2) and a graphitic carbon nitride-loaded ceria (CeO2/GCN) nanocomposite were synthesized using a straightforward and efficient method and characterized by XRD, FTIR, SEM, TEM, TGA, and BET analyses. These techniques confirmed that CeO2 was effectively supported on the surface of GCN, with particle sizes of the CeO2/GCN composite in the range of 10–15 nm and a pore size of 3.33 nm. The photocatalytic activity of the CeO2/GCN nanocomposite and CeO2 NPs in the degradation of methyl red dye under sunlight radiation was studied using UV–visible spectroscopy. A noticeable red shift in the CeO2/GCN nanocomposite compared to pure CeO2 NPs suggests a reduction in its band gap energy, calculated at 3.90 eV for CeO2 NPs and 2.97 eV for the CeO2/GCN nanocomposite. This band gap reduction enhances the photocatalytic degradation process, achieving a removal efficiency of 99.92% within a short irradiation time of 40 min for the CeO2/GCN nanocomposite, compared to 69.47% for CeO2 NPs. These findings indicate that graphitic carbon nitride significantly enhances the photocatalytic properties of CeO2 NPs. Full article
(This article belongs to the Special Issue Science and Technology for Water Purification, 2nd Edition)
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20 pages, 9983 KiB  
Article
Comprehensive Analysis of Microplastic Abundance in Macrophytes, Macrophyte-Associated Sediments, and Water in Tropical Coastal Lagoons in Sri Lanka
by R. M. L. I. Rathnayake, A. A. D. Amarathunga, D. S. M. De Silva, A. R. McGoran, A. Bakir, D. B. Sivyer, C. Reeve and S. R. C. N. K. Narangoda
Water 2025, 17(2), 157; https://doi.org/10.3390/w17020157 - 9 Jan 2025
Viewed by 296
Abstract
The prevalence and fate of microplastics in macrophytes are insufficiently understood, and data on the abundance of microplastic (MP) accumulation in macrophyte ecosystems are urgently needed to fill this knowledge gap. The main objectives of this study were to quantify and characterize the [...] Read more.
The prevalence and fate of microplastics in macrophytes are insufficiently understood, and data on the abundance of microplastic (MP) accumulation in macrophyte ecosystems are urgently needed to fill this knowledge gap. The main objectives of this study were to quantify and characterize the microplastics that accumulate in macrophytes, associated sediments, and water in Negombo Lagoon, Sri Lanka. The investigation was conducted with specialized sampling and extraction techniques. Microplastics were detected by the fluorescence tagging of polymers using Nile red, and polymer identification was conducted by ATR-µFTIR and ATR-FTIR. This study revealed variations in microplastic abundance across different macrophyte species. Gracilaria sp. had a higher abundance of 9 ± 3 items g−1 wet weight, followed by Chaetomorpha sp. at 8 ± 3 items g−1 wet weight and Halodule pinifolia at 6 ± 1 items g−1 wet weight. The root surfaces of these species had slightly similar levels of abundance. Both blue and transparent microplastics were predominant. Fragments (>47%) were found at a higher percentage in macrophyte samples, but high fiber contents (>60%) were found in associated sediment and water samples. Nevertheless, macrophyte samples contained a higher percentage of fragments in the size range of 50–150 μm. This comprehensive study contributes to expanding our awareness regarding the influence of microplastic pollution on macrophyte ecosystems. Full article
(This article belongs to the Section Water Quality and Contamination)
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