Featured
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| Open AccessTriboelectric sensor with ultra-wide linear range based on water-containing elastomer and ion-rich interface
The incompatibility between high sensitivity and a wide linear range has hindered the development of sensors. Here, the authors propose a pressure sensor that combines a water-containing triboelectric elastomer with gradient-based microchannels, achieving an ultra-wide linear range and high sensitivity simultaneously.
- Siyao Qin
- , Peng Yang
- & Xiangyu Chen
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Article
| Open AccessA blockchain consensus mechanism for real-time regulation of renewable energy power systems
For control systems, blockchain usually exhibits a trade-off between security and real-time performance. Here, authors propose a new mechanism that utilizes multi-party computation and verification with prediction, specifically tailored for real-time security control of renewable energy power systems.
- Yi Yu
- , Guo-Ping Liu
- & Yu-Zhong Li
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Article
| Open AccessSurface reconstruction of wide-bandgap perovskites enables efficient perovskite/silicon tandem solar cells
The defect-rich surface of wide-bandgap perovskite solar cells leads to severe interfacial carrier loss and phase segregation. Here, the authors reconstruct the surface through nano-polishing followed by passivation, achieving certified efficiency of 33.1% for perovskite/silicon tandem solar cells.
- Zheng Fang
- , Bingru Deng
- & Xipeng Xu
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Article
| Open AccessTackling activity-stability paradox of reconstructed NiIrOx electrocatalysts by bridged W-O moiety
One challenge remaining in the electrocatalysts for acidic water electrolysis is the activity-stability paradox. Here, the authors report a facile approach to tackle the challenge by introducing a bridged W-O moiety in NiIrOx electrocatalyst, enhancing the efficacy and stability simultaneously.
- Muhammad Imran Abdullah
- , Yusheng Fang
- & Haijiang Wang
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Article
| Open AccessTransforming CO2 into advanced 3D printed carbon nanocomposites
This work develops a method to sequester carbon emissions into valuable 3D printed materials. By combining a reactor cascade with advanced additive manufacturing, this system offers the ability for carbon utilization at scale, a crucial step for addressing climate change.
- Bradie S. Crandall
- , Matthew Naughton
- & Feng Jiao
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Article
| Open AccessAn anticoagulant supercapacitor for implantable applications
Implantable supercapacitors are promising for the use as energy supply devices within the body, but their utility is hindered by coagulation and thrombosis. Here, the authors report an implantable supercapacitor that exhibits good anticoagulant properties and cycling stability.
- Xiangya Wang
- , Meimei Yu
- & Fen Ran
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Article
| Open AccessDirect observation of ultrafast cluster dynamics in supercritical carbon dioxide using X-ray Photon Correlation Spectroscopy
A transition from ballistic to diffusive motion within 10 ps is observed in supercritical carbon dioxide with X-ray photon correlation spectroscopy. Collisions of unbound molecules with clusters are responsible for the ultrafast momentum exchange.
- Arijit Majumdar
- , Haoyuan Li
- & Matthias Ihme
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Article
| Open AccessZeolite membrane with sub-nanofluidic channels for superior blue energy harvesting
Blue energy from salinity gradients provides sustainable power. Here, authors show that NaX zeolite membranes deliver high power density for blue energy, outperforming conventional membranes and functioning effectively in challenging conditions, including high alkalinity.
- Ruicong Wei
- , Xiaowei Liu
- & Zhiping Lai
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Article
| Open AccessTailoring tetrahedral and pair-correlation entropies of glass-forming liquids for energy storage applications at ultralow temperatures
Aqueous solutions that can enter glassy state have excellent anti-freezing property. Here the authors propose a glass-forming liquid by tailoring tetrahedral and pair-correlation entropies to achieve ultralow temperature energy applications.
- Meijia Qiu
- , Peng Sun
- & Wenjie Mai
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Article
| Open AccessIdentifying key intermediates for the oxygen evolution reaction on hematite using ab-initio molecular dynamics
Hematite is a promising material for photoelectrochemical water splitting, but its mechanisms are not well understood. Here, the authors report a detailed mechanism, identifying key reaction intermediates and highlighting the influence of solvent water and oxygen desorption on the reaction pathways.
- Shuai Xu
- , Jiarui Yang
- & Yuliang Li
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Article
| Open AccessAtomically engineered interfaces inducing bridging oxygen-mediated deprotonation for enhanced oxygen evolution in acidic conditions
Efficient and stable electrocatalysts for acidic oxygen evolution are essential for proton exchange membrane electrolyzers. Here, the authors report Ru–O–Ir atomic interfaces that enable bridging oxygen-mediated deprotonation pathways, overcoming the activity/stability trade-off in acidic oxygen evolution.
- Han Wu
- , Jiangwei Chang
- & Siyu Lu
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Article
| Open AccessCorrosion-resistant NiFe anode towards kilowatt-scale alkaline seawater electrolysis
Large-scale alkaline seawater electrolysis demands robust anodes for efficient hydrogen production. Here, the authors report a NiFe layered double hydroxide anode with intercalated phosphates, achieving stable performance at 1.0 A cm−2 for over 1,000 hours, offering improved durability and activity.
- Xiaogang Sun
- , Wei Shen
- & Shi-Zhang Qiao
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Article
| Open AccessHighly efficient narrow bandgap Cu(In,Ga)Se2 solar cells with enhanced open circuit voltage for tandem application
Pure CuInSe2 solar cells suffer from strong interfacial carrier recombination. Here, the authors introduce a wide U-shaped double Ga grading with a minimum bandgap of 1.01 eV and achieve certified device efficiency of 20.26%, making it highly suitable for tandem solar cell applications.
- Junjun Zhang
- , Zengyang Ma
- & Xudong Xiao
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Article
| Open AccessPd hydride metallene aerogels with lattice hydrogen participation for efficient hydrogen evolution reaction
The rational design of hydrogen evolution catalysts is crucial for advancing green energy technologies. Here, the authors report a lattice hydrogen-involved mechanism on β-Pd hydride metallene aerogels, which separate adsorption and desorption sites and thus show enhanced electrocatalytic performance.
- Hengjia Wang
- , Ying Qin
- & Chengzhou Zhu
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Article
| Open AccessCarbon footprint distributions of lithium-ion batteries and their materials
A cost-based method to assess lithium-ion battery carbon footprints was developed, finding that sourcing nickel and lithium influences emissions more than production location. This aids in designing green industrial policy.
- Leopold Peiseler
- , Vanessa Schenker
- & Tobias Schmidt
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Article
| Open AccessNoninvasive rejuvenation strategy of nickel-rich layered positive electrode for Li-ion battery through magneto-electrochemical synergistic activation
Severe Ni/Li antisite disorder in nickel-rich layered oxides leads to structural degradation and performance decay in Li-ion batteries. Here, authors report a noninvasive strategy of magnetoelectrochemical synergistic activation to realize ordered cation rearrangement and recovery battery capacity.
- Haochen Gong
- , Yu Cao
- & Jie Sun
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Article
| Open AccessOperando visualisation of lithium plating by ultrasound imaging of battery cells
The authors have demonstrated a method for real-time imaging of the interior of a battery using ultrasound imaging. This approach reveals effects that hinder fast charging, enabling researchers to develop new batteries and optimize their utilization.
- David Wasylowski
- , Heinrich Ditler
- & Dirk Uwe Sauer
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Article
| Open AccessRevealing how internal sensors in a smart battery impact the local graphite lithiation mechanism
Batteries equipped with sensors are promising to optimize usage and lifetime. Here, the authors show that an internal optical fiber induces delayed graphite reaction kinetics and conclude that a bulky intrusive sensor might measure a local disrupted behavior rather than the true battery state.
- Annabel Olgo
- , Sylvie Genies
- & Sandrine Lyonnard
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Article
| Open AccessManipulating C-C coupling pathway in electrochemical CO2 reduction for selective ethylene and ethanol production over single-atom alloy catalyst
Manipulating the carbon-carbon coupling pathway in CO2 electroreduction is vital yet challenging. Here, by studying two model copper-based catalysts with distinct ethylene and ethanol selectivity, authors investigate the mechanistic origins for symmetric and asymmetric carbon-carbon coupling.
- Shifu Wang
- , Fuhua Li
- & Bin Liu
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Article
| Open AccessTailoring high-performance bipolar membrane for durable pure water electrolysis
Bipolar membrane electrolyzers hold promise for water electrolysis but are limited by poor water dissociation and interface stability. Here, the authors report poly(terphenyl alkylene)-scaffold bipolar membranes that enhance water dissociation efficiency and enable durable pure water electrolysis.
- Weisheng Yu
- , Zirui Zhang
- & Tongwen Xu
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Article
| Open AccessGradient-porous-structured Ni-rich layered oxide cathodes with high specific energy and cycle stability for lithium-ion batteries
The generation of cracks in polycrystalline Ni-rich layered lithium transition metal oxides presents numerous challenges for their use in batteries. Here, authors propose a gradiently distributed pores structure within the oxide secondary particles, reducing internal strain accumulation.
- Zhiyuan Li
- , Yong Wang
- & Linsen Li
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Article
| Open AccessClimate change and its influence on water systems increases the cost of electricity system decarbonization
The authors link water and electricity system models to evaluate how the electric grid can both adapt to climate change impacts and decarbonize, while also accounting for dependencies and climate vulnerabilities of the closely coupled water sector.
- Julia K. Szinai
- , David Yates
- & Patricia Hidalgo-Gonzalez
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Article
| Open AccessGenerative learning assisted state-of-health estimation for sustainable battery recycling with random retirement conditions
Data scarcity and heterogeneity impede the estimation of retired battery capacity. Here, Tao et al. propose a generative learning method that extends measured data space, potentially reducing curation time, cost and facilitating their sustainable reuse and recycling.
- Shengyu Tao
- , Ruifei Ma
- & Guangmin Zhou
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Article
| Open Access3T-VASP: fast ab-initio electrochemical reactor via multi-scale gradient energy minimization
Ab-initio methods often require many steps before the simulated structure can escape trivial local energy minimums. Here, authors show that tiered tensor transform (3T) can be used to explore complex chemical reactions with modest count of DFT steps.
- Jonathan P. Mailoa
- , Xin Li
- & Shengyu Zhang
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Article
| Open AccessTwin-distortion modulated ultra-low coordination PtRuNi-Ox catalyst for enhanced hydrogen production from chemical wastewater
Efficient catalysts are key to advancing the hydrogen economy, particularly for the hydrogen evolution reaction. Here, the authors report that ultra-low coordinated hollow PtRuNi-Ox nanocages offer comparable catalytic performance and stability in both freshwater and wastewater conditions.
- Yue Zhang
- , Xueqin Mu
- & Zhuhui Dai
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Article
| Open AccessMechanical shutdown of battery separators: Silicon anode failure
Here, authors identify mechanical shutdown of separators as an overlooked contributor to Si full cell degradation. A high modulus separator prevents pore collapse from Si expansion, improving capacity retention and providing insights to enhance Si full cell performance.
- Ji-Young Seo
- , Suhwan Kim
- & Sang-Young Lee
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Article
| Open AccessIntegrable utilization of intermittent sunlight and residual heat for on-demand CO2 conversion with water
Residual industrial heat could be harnessed as an energy source for CO2 conversion. Here the authors present a method for storing electrons and hydrogen in catalysts using light and water, which are then released upon heating to enable CO2 reduction with intermittent sunlight and residual heat.
- Xianjin Shi
- , Wei Peng
- & Yujie Xiong
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Article
| Open AccessA green solvent enables precursor phase engineering of stable formamidinium lead triiodide perovskite solar cells
The use of harmful solvents to fabricate stable devices hampers the commercialization of perovskite solar cells. Here, the authors introduce a biorenewable solvent system and precursor-phase engineering to realize stable formamidinium lead triiodide-based solar cells.
- Benjamin M. Gallant
- , Philippe Holzhey
- & Henry J. Snaith
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Article
| Open AccessMacroscopically uniform interface layer with Li+ conductive channels for high-performance Li metal batteries
Here, authors report a macroscopical grain boundary-free interface layer with microscopic Li + -selective conductive channels enables the ultra-dense Li metal deposition, resulting in a high energy density (506 Wh kg−1) and long cycle life (160 cycles) pouch cell performance.
- Qian Chen
- , Binyin Gao
- & Yongji Gong
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Article
| Open AccessA core–shell fiber moisture-driven electric generator enabled by synergetic complex coacervation and built-in potential
The authors present a core–shell fiber moisture-driven electric generator by a synergetic complex coacervation and built-in potential strategy, enabling self-powered human interactive sensors and synaptic devices.
- Guangtao Zan
- , Wei Jiang
- & Cheolmin Park
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Article
| Open AccessDesign towards recyclable micron-sized Na2S cathode with self-refinement mechanism
Authors report that micron-sized Na2S particles can be self-refinement into nanoparticles during the initial cycle under rapid solid-liquid-solid conversion, which facilitates the development of Na-free anode systems in room-temperature sodium-sulfur batteries.
- Suwan Lu
- , Yang Liu
- & Xiaodong Wu
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Article
| Open AccessA self-healing plastic ceramic electrolyte by an aprotic dynamic polymer network for lithium metal batteries
Self-healing is an appealing property for solid-state battery electrolytes to combat Li metal dendrites that pierce through the solid electrolyte. Here, authors report a self-healing electrolyte and observe its self-repairing kinetics in real-time using advanced microscopy.
- Yubin He
- , Chunyang Wang
- & Huolin L. Xin
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Article
| Open AccessEffect of adaptive cruise control on fuel consumption in real-world driving conditions
Efficient automated driving technology to improve upon human driving behaviour offer a promising pathway to energy and fuel savings. Here, authors analyse real-world data to determine how adaptive cruise control affects fuel consumption and identify specific driving situations where it can be optimized.
- Ayman Moawad
- , Matthew Zebiak
- & Aymeric Rousseau
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Article
| Open AccessBioelectrocatalytic carbon dioxide reduction by an engineered formate dehydrogenase from Thermoanaerobacter kivui
Thermoanaerobacter kivui-drived CO2 reductase (TkHDCR) requires hydrogen as substrate, which can lead to safety issue. Here, the authors engineered TkHDCR into an electro-responsive carbon dioxide reductase to harvest electrons from either an external mediator or a polarized electroactive surface.
- Weisong Liu
- , Kuncheng Zhang
- & Lingling Zhang
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Article
| Open AccessBreaking the capacity bottleneck of lithium-oxygen batteries through reconceptualizing transport and nucleation kinetics
To realize the theoretical energy density of lithium-oxygen batteries, this work uses the relationship between microscopic phenomena and macroscopic performance. By adjusting lithium-ion concentration, alignment of transport and nucleation kinetics improves and discharge capacity of the electrodes maximized.
- Zhuojun Zhang
- , Xu Xiao
- & Peng Tan
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| Open AccessInterface engineering enabling thin lithium metal electrodes down to 0.78 μm for garnet-type solid-state batteries
Fabricating thin lithium electrodes is challenging due to lithium’s fragility and viscosity. Here, authors convert surface Li2CO3 on Ta-doped Li7La3Zr2O12 to a lithiophilic layer via trifluoromethanesulfonic acid treatment, enabling precise control over lithium metal negative electrode thickness.
- Weijie Ji
- , Bi Luo
- & Ji Liang
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Article
| Open AccessA Ni4O4-cubane-squarate coordination framework for molecular recognition
Materials for multifunctional molecular recognition are essential in industry. Here, the authors present a cost-effective, stable and multifunctional Ni-cubane MOF that effectively separates hexane isomers, xenon/krypton, and carbon dioxide/nitrogen.
- Qingqing Yan
- , Shuyi An
- & Jiangfeng Du
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Article
| Open AccessHybridizing anomalous Nernst effect in artificially tilted multilayer based on magnetic topological material
The anomalous Nernst effect is a key for transverse thermoelectric applications. Here, the authors show an intense performance improvement of the anomalous Nernst effect via hybrid actions with the off-diagonal Seebeck effect in artificial materials.
- Takamasa Hirai
- , Fuyuki Ando
- & Ken-ichi Uchida
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| Open AccessHydrogen radical-boosted electrocatalytic CO2 reduction using Ni-partnered heteroatomic pairs
Commercially viable catalytic CO2 electroreduction to CO would enable many green technologies, yet it is impeded by the initial hydrogenation step of CO2. Here, the authors report Ni-Cd dual atom catalysts with complementary properties of favorable adsorption of CO2 and H to overcome this barrier.
- Zhibo Yao
- , Hao Cheng
- & Zhenyu Sun
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Article
| Open AccessA self-reactivated PdCu catalyst for aldehyde electro-oxidation with anodic hydrogen production
A low-potential dual-side hydrogen production system is more efficient than water splitting but suffers from stability issues. Here, the authors report a self-reactivating PdCu catalyst that operates stably for 120 h, offering an alternative solution for energy-efficient hydrogen production.
- Ming Yang
- , Yimin Jiang
- & Yuqin Zou
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Article
| Open AccessUnderstanding pillar chemistry in potassium-containing polyanion materials for long-lasting sodium-ion batteries
The sodium storage mechanism of K-containing polyanion compounds is intricate and unclear. Here, the authors reveal that the residual K+ pillars uphold K-containing polyanion structure upon sodium storage, enabling long-term cycling stability.
- Wenyi Liu
- , Wenjun Cui
- & Jinping Liu
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Article
| Open AccessProton-exchange induced reactivity in layered oxides for lithium-ion batteries
The sensitivity of Li-ion battery materials to moisture complicates their synthesis, storage, processing and recycling. Here, authors show that protonation causes structural instability in LiNixCoyMn1-x-yO2 (0 <x,y < 1) and that controlled H+ and Li+ concentration in aqueous processing is critical.
- Panpan Xu
- , Xingyu Guo
- & Zheng Chen
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Article
| Open AccessHermetic hydrovoltaic cell sustained by internal water circulation
In this work, authors developed a hermetic hydrovoltaic cell that generates electricity from ambient heat without consuming water. The device operates continuously for 160 h, unaffected by external conditions like wind and light, making it potentially suitable for various challenging environments.
- Renxuan Yuan
- , Huizeng Li
- & Yanlin Song
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Article
| Open AccessDistributed direct air capture of carbon dioxide by synergistic water harvesting
Direct air capture of CO2 suffers from high energy consumption. Here, the authors use co-harvested water as in situ vapor purge to regenerate the sorbents, achieving over 98% recovery of the adsorbed CO2, more than 20% reduction in energy penalty, and synergistic production of CO2 and water.
- Yongqiang Wang
- , Longbing Qu
- & Gang Kevin Li
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Article
| Open AccessRobust bendable thermoelectric generators enabled by elasticity strengthening
The authors strengthen the elasticity of Ag2Se by microstructure engineering approach, realizing bendability of the thermoelectric generator for at least 1,000,000 times at a tiny bending radius of 3 mm with a high power density.
- Wenjun Ding
- , Xinyi Shen
- & Yanzhong Pei
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Article
| Open AccessParallel multi-stacked photoanodes of Sb-doped p–n homojunction hematite with near-theoretical solar conversion efficiency
Developing efficient and transparent photoanodes for solar water splitting is crucial for advancing clean energy technologies. Here, the authors report Sb-doped p–n homojunction hematite photoanodes that achieve high transparency and a stable photocurrent density of 4.21 mA cm–2.
- Chenyang Xu
- , Hongxin Wang
- & Hemin Zhang
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Article
| Open AccessMicro-homogeneity of lateral energy landscapes governs the performance in perovskite solar cells
The energy disorders in the lateral direction of the junction in large-area photovoltaic modules are largely overlooked. Here, authors employ organic amidinium passivators to suppress the micro-inhomogeneity in the lateral energy landscapes and achieve high performance stable perovskite solar cells.
- Pengju Shi
- , Bin Ding
- & Jingjing Xue
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Article
| Open AccessA tripartite synergistic optimization strategy for zinc-iodine batteries
Here, authors propose a tripartite synergistic optimization strategy involving cathode host, electrolyte additive, and in-situ anode protection, which enables the zinc-iodine batteries exhibit high capacity, superior energy density, and ultralong cycle life.
- Weibin Yan
- , Ying Liu
- & Zifeng Lin
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Article
| Open AccessAn assessment of China’s methane mitigation potential and costs and uncertainties through 2060
This paper assesses methane emission reduction sources, costs, and uncertainties in China’s methane pathways through 2060. It identifies significant cost-effective methane reduction potential in the energy and agriculture sectors as early as 2030.
- Nina Khanna
- , Jiang Lin
- & Wenjun Wang